The mixing of chemicals has come a long way. Once, the hand mixing of large batches resulted in inconsistent mixes and waste. That was then. This is now: Highly precise, computerized in-line machines make better-quality emulsions, saving money on labor and transport.
A finer emulsion is just part of the picture. Even with a better-quality blend, chemicals often are mixed in large batches, presenting storage, transportation and degradation problems. Water is a large component of many chemical mixtures and emulsions ," as much as 90 percent in most cases ," so plants must devote considerable space and resources to storage. It also costs more to transport these highly diluted chemicals. Some plants do not have the capability to create these finishes on-site. Finally, large quantities of stored chemicals are subject to degradation and bacteria growth. Such large inventories often contribute to waste.
The textile industry began using technologies such as static (motionless) mixing and in-line (continuous blend) mixing to address these challenges and now is beginning to reap the rewards from the investments. The lessons learned in textiles can be applied to many chemical processing industries.
No moving parts
The first static mixers were developed in the 1960s. A static mixer has no moving parts and works extremely well in creating emulsions ," stable suspensions of one liquid in a second immiscible liquid. Static mixers create stable emulsions because they reduce the particles to a smaller size so they stay together in a stronger bond for a longer period of time.
Emulsion creation is critical to numerous chemical processes. In textiles, emulsions are crucial to finishes ," chemical treatments applied to a yarn or fabric to produce a desired effect. For example, chemical finishes can make towels softer, slacks stain-resistant and blue jeans a deeper blue.
The diagram illustrates the setup of a typical in-line mixing system.
In general, static mixers work by dividing streams of ingredients that need to be mixed. The ingredient stream typically is forced through the static mixer by a pump. The ingredients then are split into substreams as they are forced through the mixer. These substreams then are recombined and divided once again. This process might be repeated numerous times.
The standard static mixer uses baffles to divide ingredients into two streams, but some static mixing designs today divide ingredients into four streams, creating a more homogenous mix. For example, if a stream of water and a stream of chemical agent "A" were pumped into the static mixer, the stream of water and the stream of agent A each would be divided into four streams. These four streams would be recombined and forced through the static mixer again. The four streams would be divided into 16 streams, and so on.
Mathematically, the equation is: N = 4n, where 4 is the number of splits in the stream, and "n" is the number of elements being mixed. As each ingredient is pumped through the static mixer, pressure is applied to keep the particle streams moving at a high rate of speed. Once the particles reach a critical Reynold's number, the common measure of turbulence, they begin to intermingle and form a uniform, consistent mix.
The smaller particles then impinge against one another according to Newton's Second Law: The acceleration of an object is directly proportional to the net force acting on it and is inversely proportional to its mass; the direction of the acceleration is in the direction of the applied net force. This "Newtonian movement" keeps the ingredients in suspension much longer.
Continuous just-in-time blending came into its own in the 1990s when static mixing was incorporated into an automated system.
To create an automated continuous mix system, the following components generally are needed: an automated pump system, flowmeters to measure chemical delivery and some type of intensive mixing. Because they are being retrofitted into existing processes, in-line mixers often have to be "back integrated" to satisfy the particular needs of a given process. The components are selected based on the volume requirements and the type and number of chemicals that have to go through them. In-line mixers can be retrofitted into a production line economically and have a footprint no larger than a typical office desk or even smaller.
The major components of a static in-line mixer used in the textile industry ," and potentially in the chemical industries ," include:
Progressive cavity pumps.
Programmable logic controllers (PLCs).
Progressive cavity pumps move the materials through the mixing process. The pumps provide the mixer with a metered, uniform flow. Typically one pump is used for each product in the mixture. The pumps are extremely versatile, capable of handling materials ranging from abrasives to clear fluids. Each progressive cavity pump can handle liquids with a viscosity as great as approximately 100,000 centipoise.
Mass flowmeters control the amount of each product pumped into the mixture. These devices provide feedback to the pumps to ensure accurate delivery. Users simply enter the proportions of each component into the computer, and the control loop ensures each mix is delivered accurately. The flowmeters also provide on-line measurement of density and temperature.
Traditional mixing devices used in the textile industry had a mixing accuracy range of error between +1 and -1 percent. With a static in-line mixing machine, this accuracy is significantly greater ," the range of error is between +0.1 percent and -0.1 percent.
The static mixer provides the machine with its uniqueness. It allows users to create more than a million mixes in a standard 10-element mixer, and it is applicable for a wide viscosity range.